SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Version 6.5

Revision Date 15.09.2020

Print Date 12.03.2021 GENERIC EU MSDS – NO COUNTRY SPECIFIC DATA – NO OEL DATA

 

 

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiers

Product name : N,N-Dimethylaniline

Product Number : 407275

Brand : MIT-IVY

Index-No. : 612-016-00-0

REACH No. : A registration number is not available for this substance as the

substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

CAS-No. : 121-69-7

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Manufacture of substances

1.3 Details of the supplier of the safety data sheet

 

Company : Mit-ivy Industry co., ltd

 

Telephone : +0086 1380 0521 2761

 

Fax : +0086 0516 8376 9139

 

1.4 Emergency telephone number

 

 

Emergency Phone # : +0086 1380 0521 2761

 

+0086 0516 8376 9139

 

 

 

 

 

 

 

 

 

 

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 3), H311 Carcinogenicity (Category 2), H351

Long-term (chronic) aquatic hazard (Category 2), H411

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Pictogram

 

Signal word Danger Hazard statement(s)

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.

H351 Suspected of causing cancer.

H411 Toxic to aquatic life with long lasting effects.

Precautionary statement(s)

P201 Obtain special instructions before use.

P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing.

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

Rinse mouth.

P302 + P352 + P312 IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/

doctor if you feel unwell.

P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable

for breathing. Call a POISON CENTER/ doctor.

Supplemental Hazard Statements

2.3 Other hazards

none

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

 

 

SECTION 3: Composition/information on ingredients

3.1 Substances

Formula : C8H11N

Molecular weight : 121,18 g/mol

CAS-No. : 121-69-7

EC-No. : 204-493-5

Index-No. : 612-016-00-0

 

Component	Classification	Concentration
N,N-dimethylaniline
	Acute Tox. 3; Carc. 2; Aquatic Chronic 2; H301, H331, H311, H351, H411	<= 100 %

For the full text of the H-Statements mentioned in this Section, see Section 16.

 

 

SECTION 4: First aid measures

4.1 Description of first-aid measures General advice

Consult a physician. Show this material safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

No data available

 

 

SECTION 5: Firefighting measures

5.1 Extinguishing  media Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Carbon oxides, Nitrogen oxides (NOx)

5.3 Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information

Use water spray to cool unopened containers.

 

 

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.

For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet- brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For disposal see section 13.

 

 

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapor or mist.

Keep away from sources of ignition – No smoking.Take measures to prevent the build up of electrostatic charge.

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

 

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Ingredients with workplace control parameters

8.2 Exposure controls

Appropriate engineering controls

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Personal protective equipment

 

Eye/face protection

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Full contact

Material: butyl-rubber

Minimum layer thickness: 0,3 mm Break through time: 480 min

Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M)

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,4 mm Break through time: 30 min

data source: MIT-IVY,
phone 008613805212761,
e-mail CEO@MIT-IVY.COM, test method: EN374

If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full- face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

 

 

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

a) Appearance Form: liquid Color: light yellow

b) Odor No data available

c) Odor Threshold No data available

d) pH 7,4 at 1,2 g/l at 20 °C

 

e) Melting

point/freezing point

f) Initial boiling point and boiling range

Melting point/range: 1,5 – 2,5 °C – lit. 193 – 194 °C – lit.

g) Flash point 75 °C – closed cup

h) Evaporation rate No data available

i) Flammability (solid, gas)

j) Upper/lower flammability or explosive limits

No data available

 

Upper explosion limit: 7 %(V) Lower explosion limit: 1 %(V)

k) Vapor pressure 13 hPa at 70 °C

1 hPa at 30 °C

l) Vapor density 4,18 – (Air = 1.0)

m) Relative density 0,956 g/cm3 at 25 °C

n) Water solubility ca.1 g/l

• o) Partition coefficient: n-octanol/water

p) Autoignition temperature

q) Decomposition temperature

log Pow: 2,62

 

No data available No data available

r) Viscosity No data available

s) Explosive properties No data available

t) Oxidizing properties No data available

9.2 Other safety information

Surface tension 3,83 mN/m at 2,5 °C

 

Relative vapor density

4,18 – (Air = 1.0)

 

 

SECTION 10: Stability and reactivity

10.1 Reactivity

No data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

Heat, flames and sparks.

10.5 Incompatible materials

Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides, Chloroformates, Halogens

10.6 Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. – Carbon oxides, Nitrogen oxides (NOx)

Other decomposition products – No data available In the event of fire: see section 5

 

 

SECTION 11: Toxicological information

11.1 Information on toxicological effects Acute toxicity

LD50 Oral – Rat – 951 mg/kg

Remarks: Behavioral:Somnolence (general depressed activity). Behavioral:Tremor. Cyanosis

LD50 Dermal – Rabbit – 1.692 mg/kg

Skin corrosion/irritation

Skin – Rabbit

Result: Mild skin irritation – 24 h

Serious eye damage/eye irritation

Eyes – Rabbit

Result: Mild eye irritation – 24 h (OECD Test Guideline 405)

Respiratory or skin sensitization

No data available

Germ cell mutagenicity

Hamster Lungs

Micronucleus test Hamster

ovary

Sister chromatid exchange

 

Rat

DNA damage

Carcinogenicity

This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.

Limited evidence of carcinogenicity in animal studies

IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

No data available

Specific target organ toxicity – single exposure

No data available

Specific target organ toxicity – repeated exposure

No data available

Aspiration hazard

No data available

Additional Information

RTECS: BX4725000

 

Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer., Damage to the eyes., Blood disorders

 

 

 

SECTION 12: Ecological information

12.1 Toxicity

Toxicity to fish LC50 – Pimephales promelas (fathead minnow) – 65,6 mg/l – 96,0 h

Toxicity to daphnia and other aquatic invertebrates

EC50 – Daphnia magna (Water flea) – 5 mg/l – 48 h

12.2 Persistence and degradability

Biodegradability Biotic/Aerobic – Exposure time 28 d

Result: 75 % – Readily biodegradable.

Ratio BOD/ThBOD < 20 %

12.3 Bioaccumulative potential

Bioaccumulation Oryzias latipes(N,N-dimethylaniline)

 

Bioconcentration factor (BCF): 13,6

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

Toxic to aquatic life with long lasting effects.

 

 

SECTION 13: Disposal considerations

13.1 Waste treatment methods Product

This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging

Dispose of as unused product.

 

 

SECTION 14: Transport information

14.1 UN number

ADR/RID: 2253 IMDG: 2253 IATA: 2253

14.2 UN proper shipping name ADR/RID: N,N-DIMETHYLANILINE IMDG: N,N-DIMETHYLANILINE IATA: N,N-Dimethylaniline

14.3 Transport hazard class(es)

ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1

14.4 Packaging group

ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards

ADR/RID: yes IMDG Marine pollutant: yes IATA: no

14.6 Special precautions for user

No data available

 

 

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

REACH – Restrictions on the manufacture, : placing on the market and use of certain

dangerous substances, preparations and articles (Annex XVII)

 

 

15.2 Chemical Safety Assessment

For this product a chemical safety assessment was not carried out

 

 

SECTION 16: Other information

Full text of H-Statements referred to under sections 2 and 3.

H301 Toxic if swallowed.

H301 + H311 + H331

Toxic if swallowed, in contact with skin or if inhaled.