Properties of m-Phenylenediamine Melting Point 64-66°C(lit.)
Boiling Point 282-284°C(lit.) Density 1,139g/cm3 Vapor Density 3.7(Vsair) Vapor Pressure 0.62mmHg(100°C) Refractive Index 1.6339
Flash Point >230°F Storage Conditions Storebelow+30°C.Solubility of 350 g/l acidity coefficient (pKa) 5.11, 2.50 (at20 ℃) form 8 pellets YellowtolighttanorbrowngrayPH color values (100 g/l, H2O, 20 ℃) water solubility of 350 g/l (25 DHS C) sensitivity AirSensit7283 brn471357inchikeywzcqruwwhstzem iveMerck14, 45-108-2 – UHFFFAOYSA – NCAS database (CASDataBaseReference) 1, 3 -
Benzenediam NIST chemical informationUses and synthetic methods of 1, 3-phenylenediamine (108-45-2). Chemical properties Colorless needle-like crystal.Soluble in water, ether and ethanol.
Mainly used as dye intermediate and epoxy resin curing agent for azo dye and acazine dye intermediate, mainly used in the manufacture of direct tanning RN, basic orange, basic brown G, direct tanning G and other dyes, and used as fur dye, in Japan, azo dye consumption of m-phenylenediamine accounts for 90% of the total consumption.It is also used as curing agent of epoxy resin, coagulant promoter of cement, and used in hair dye, mordant, color agent and so on.Used as an analytical reagent, resin curing agent and polymer inhibitor, also used in the synthesis of dyes for spectrophotometric determination of nitrite, determination of bromate, bromide, chromate, ozone, gold, copper, dichromate, iron, oxygen and platinum, determination of active chlorine, chromium, iridium, nitrite and palladium.Production method: nitrobenzene is nitrated by mixed acid into m-dinitrobenzene, o-dinitrobenzene, p-dinitrobenzene mixture, and then by sodium sulfite and liquid alkali refining m-dinitrobenzene, and then iron powder reduction or hydrogenation reduction to m-phenylenediamine.
Raw material consumption quota: nitrobenzene 1400kg/t, nitric acid 787kg/t, sulfuric acid (98%) 780kg/t, iron powder 3083kg/t.Class Toxic Substances Toxicity Grade High Toxicity Acute Toxicity Oral – Rats LD50:280 mg/kg;Oral administration – mouse LD50:67.7 mg/kg flammability hazard characteristics Flame flammability;When heated, toxic aniline gas is released. ChemicalBook room is ventilated and dried at low temperature.Separate storage and transportation of fire extinguishing agents, aerosol water, carbon dioxide, sandy soil Occupational standard TWA 0.1mg/m3 Safety information Dangerous Goods Labeling T,N Hazardous Category Code 23/24/25-36-43-50/53-68-40 Safety Description 28-36/37-45-60-61-28A Dangerous Goods Transport No. UN1673No. 6.1 / PG3WGKGermany2RTECS SS7700000F8-10-23 spontaneous combustion temperature of 560 ° CTSCAYesHazardClass6.1 PackingGroupIII customs code 29215119 toxic substance data 108-45-2 (HazardoToxic LD50inrats usSubstancesData) (mg/kg) : 650 orally;1, 3-diaminobenzene (Chinese) Sigmaaldrich (English) Acros (English) Alfa (English) Alfa (English) m – Phenylenediamine Price (Reagent Grade)
Update Date Product Number Product Name CAS Number Package Price 202020/03/18 A15339 m-phenylenediamine,98% 108-45-2250G320 2020/03/1830921 m-phenylenediamine,99+% M-phenylenediamine,99+% 108-45-2250G320 yuan m-phenylene diamine upstream and downstream product information upstream raw materials for sulfuric acid – > resorcinol dinitrobenzene downstream products — – > 1, 3 – two chlorobenzene > fluconazole – > alkaline orange 2 – - > 4 – amino – N, N – dimethyl aniline – > 1, fluorine benzene – > 2, 4-2 – fluoro aniline > amino acetanilide between direct black FF > — – > directlyBlack 19 – > weak acid red brown V > disperse red 74 — – > direct black 38 – > direct fast black G — – > alkaline orange > directly blended brown D – RS — – > direct red brown R > reactive flavine M – 7 G – > acid black acid black 210-234 – a – > > 4 – [[5 - (amino carbonyl) - 1 - ethyl - 1, 6 - dihydro -2 - hydroxy - 4 - methyl - 6 - oxygen generation - 3 - pyridyl) azo] – 6 – [(4, 6 - dichloro - 1,3,5 - triazine - 2 - base) amino] – 1, 3 – benzene disulfonic acid disodium salt — – > direct yuan grey AB > direct black ANBN > alkaline brown G — – > alkaline brown one
Post time: Apr-21-2021